石油化工设备技术 ›› 2023, Vol. 44 ›› Issue (1): 31-34.doi: 10.3969/j.issn.1006-8805.2023.01.006

• 腐蚀与防护 • 上一篇    下一篇

催化裂化装置稳定塔底重沸器管束腐蚀和选材分析

佘 锋   

  1. 中国石化工程建设有限公司,北京 100101
  • 收稿日期:2022-10-13 接受日期:2022-12-31 出版日期:2023-01-15 发布日期:2023-03-16
  • 作者简介:佘锋,男,2012年毕业于钢铁研究总院材料学专业,硕士,主要从事炼油装置选材与腐蚀分析工作,高级工程师。

On Corrosion and Material Selection of Reboiler Bundles at the Bottom of Stabilizer in Catalytic Cracking Unit

She Feng   

  1. SINOPEC Engineering Incorporation, Beijing, 100101
  • Received:2022-10-13 Accepted:2022-12-31 Online:2023-01-15 Published:2023-03-16

摘要: 通过了解20套催化裂化装置稳定塔底重沸器的设计条件、操作运行及使用情况,总结归纳出稳定塔底重沸器管束在应用过程中主要失效形式为硫化物腐蚀和振动磨损/断裂。影响硫化物腐蚀的主要因素是上部管束形成气相空间或结垢,造成管束外壁温度大幅升高、硫化物浓度增加,产生严重的腐蚀问题;影响管束振动的主要因素是换热器的结构设计、工艺条件和操作控制。结合现场使用情况、标准规范和设计经验,提出防腐和防振双重措施,解决了重沸器管束的泄漏问题。

关键词: 催化裂化装置, 稳定塔底重沸器管束, 腐蚀, 选材

Abstract: Through understanding the design conditions, operation and use of reboiler bundles at the bottom of the stabilizers in 20 sets of catalytic cracking units, it is summarized that the main failure forms of reboiler bundles at the bottom of the stabilizers in the application process are sulfide corrosion and vibration wear/fracture. The main factors affecting sulfide corrosion are the formation of gas phase space or scaling in the upper tube bundle, resulting in a significant increase in the temperature of the outer wall of the tube bundle and the increase in sulfide concentration, which produces serious corrosion problems; the main factors affecting the vibration of the tube bundle are the structural design, process conditions and operation control of the heat exchanger. Combined with the field application, standard specifications and design experience, the dual measures of corrosion prevention and vibration control are proposed to solve the leakage problem of reboiler tube bundles.

Key words: catalytic cracking unit/CCU, reboiler bundles at the bottom of stabilizer, corrosion, material selection