石油化工设备技术 ›› 2024, Vol. 45 ›› Issue (3): 18-21,26.doi: 10.3969/j.issn.1006-8805.2024.03.004

• 静设备 • 上一篇    

液化石油气脱硫反应分离器的设计与开发

张竹梅   

  1. 中国石化工程建设有限公司,北京 100101
  • 收稿日期:2024-03-03 接受日期:2024-04-30 出版日期:2024-05-15 发布日期:2024-07-12
  • 作者简介:张竹梅,女,1994年毕业于大连理工大学化学工程专业,工学学士,主要从事气体加工装置的工艺开发和设计工作,高级工程师。
  • 基金资助:
    中国石化工程建设有限公司(批准号:RD-20-R007)资助的课题

Design and Development of LPG Desulfurization Reaction Separator

Zhang Zhumei   

  1. SINOPEC Engineering Incorporation, Beijing, 100101
  • Received:2024-03-03 Accepted:2024-04-30 Online:2024-05-15 Published:2024-07-12

摘要: 在油转化结构调整中,炼油企业通过多产催化液化石油气获得更多的轻烃加工原料。液化石油气脱硫装置是轻烃加工的重要处理装置,而液化石油气脱硫反应分离器则是其关键设备。近年来,随着装置大型化发展,液化石油气脱硫反应分离器的设计与开发成为了工程设计的重点。文章介绍了脱硫反应分离器的发展和工艺特点,提出通过过程强化微混式反应分离器的技术开发减小设备体积,同时采用喷射混合强化传质与破乳聚结分离耦合技术以及模块化设计的技术方案,将液化石油气脱硫反应、传质与分离过程集成化,使脱硫反应分离器在设备体积、安装布置等方面具有显著优点,以适应装置大型化发展的需要。文章分析和对比了3种液化石油气脱硫反应分离器设计方案,综合比较采用微混式反应分离器占地少、设备质量小,可满足装置扩能改造等项目的要求。

关键词: 液化石油气, 脱硫, 大型化, 反应分离器, 传质分离, 过程强化, 微混

Abstract: In oil conversion structure adjustment, refining companies can get more raw materials for light hydrocarbon processing by producing more catalytic liquefied petroleum gas (LPG). LPG desulfurization device is an important unit for light hydrocarbon processing and LPG desulfurization reaction separator is its key equipment. In recent years, with the development of large-scale unit, the design and development of LPG desulfurization reaction separator has become the focus of engineering design. This paper introduces the development and process characteristics of desulfurization reaction separator and proposesdeveloping micro-mixed reaction separator through process enhancement technology to reduce device volume. Meanwhile, it adopts the coupling technology of jet mixture-enhanced mass transfer and milk-breaking coalescence and modular design. Through the integration of desulfurization reaction, mass transfer and separation process, the desulfurization reaction separator has significant advantages in equipment volume and installation layout, which can adapt to the needs of large-scale device development. The paper compares and analyzes the design scheme of the three types of LPG desulfurization reaction separators. Through comprehensive comparison, the micro-mixed reaction separator occupies less space and has less equipment weight, which can meet the requirements of the expansion and revamp of the unit.

Key words: liquefied petroleum gas/LPG, desulfurization, large scale, reaction separator, transmission separation, process intensification, micro-mixed