石油化工设备技术 ›› 2022, Vol. 43 ›› Issue (3): 37-42.doi: 10.3969/j.issn.1006-8805.2022.03.007

• 材料与焊接 • 上一篇    下一篇

MTO装置甲醇转化反应器顶封头裂纹故障分析

秦春秋,王家纯   

  1. 中国石化中原石油化工有限责任公司,河南 濮阳 457001
  • 收稿日期:2021-06-02 接受日期:2022-04-29 出版日期:2022-06-22 发布日期:2022-06-22
  • 作者简介:秦春秋,男,1988年毕业于成都科技大学化工机械专业,学士,主要负责设备运行与管理技术方面的工作,现任公司高级专家,正高级工程师。

Fault Analysis of Crack on the Top Head of MTO Reactor

Qin Chunqiu, Wang Jiachun   

  1. SINOPEC Zhongyuan Petrochemical Corp. Ltd., Puyang, Henan, 457001
  • Received:2021-06-02 Accepted:2022-04-29 Online:2022-06-22 Published:2022-06-22

摘要: 某甲醇制烯烃(MTO)装置反应器在运行过程中, 顶封头焊缝出现裂纹, 造成产品气泄漏。随后的停车大检修期间, 对反应器进行检验, 在泄漏裂纹焊缝附近又发现1条未贯穿裂纹。对未贯穿裂纹进行取样, 并委托专业检验单位对裂纹进行宏观检查和化学成分、 铁素体含量、 硬度、 金相、 断口、 射线能谱等微观分析, 从反应器的设计、 制造、 安装、 使用情况等方面对裂纹的成因进行了分析探讨。结果显示: 裂纹具有沿晶开裂的特征; 奥氏体不锈钢焊接特性和高温特性产生的高温蠕变以及顶部椭球形封头应力分布特征存在的失稳结构是裂纹产生的内在原因, 顶封头因保温失效而产生温差应力瞬时峰值是裂纹产生的外部诱因。

关键词: MTO装置, 反应器顶封头, 奥氏体不锈钢, 焊缝裂纹, 故障分析

Abstract: In the running process of the reactor in an MTO plant, cracks appeared in the top seal head welds, resulting in product gas leakage. During the subsequent downtime overhaul, the reactor was inspected andanother non-through crack flaw was found nearby the same leakage crack welding seam. By taking a sample from the non-through crack, a professional inspection company was entrusted to conduct macroscopic inspection of cracks and microscopic analysis of chemical composition, ferrite content, hardness, metallurgy, fracture, radiographic energy spectrum and so forth. The causes of cracks were analyzed and discussed in terms of reactor design, manufacturing, installation, and service conditions. The results indicated that the cracks had the characteristics of intergranular cracking; the high temperature creep generated by the features of austenitic stainless steel welding and high temperature conditions and the structure instability in the hemi-ellipsoid head stress distribution were the internal causes of the cracking. The temperature difference stress instantaneous peak due to insulation failure of the top seal head was the external cause of the cracking.

Key words: MTO plant, top head of reactor, austenitic stainless steel, weld metal cracking, fault analysis