石油化工设备技术 ›› 2025, Vol. 46 ›› Issue (5): 1-8.doi: 10.3969/j.issn.1006-8805.2025.05.001

• 静设备 •    

高速文丘里洗涤器净化PSA原料气的性能研究

史 俭1,薛 楠2,钱运东3,李济辰2,张毅文4   

  1. 1. 中国石油化工股份有限公司天津分公司,天津 300270;
    2. 中国石化工程建设有限公司,北京 100101;
    3. 华东理工大学,上海 200237;
    4. 上海米素环保科技有限公司,上海 200237
  • 收稿日期:2025-02-17 修回日期:2025-08-15 接受日期:2025-08-29 出版日期:2025-09-15 发布日期:2025-09-16
  • 通讯作者: 钱运东 E-mail:shijian.tjsh@sinopec.com
  • 作者简介:史俭,男,2003年毕业于沈阳化工大学过程装备和控制工程专业,学士,现从事设备管理工作,高级工程师。

Study on the Purification Performance of High-speed Venturi-type Purifier on PSA Feed Gas

Shi Jian1, Xue Nan2, Qian Yundong3, Li Jichen2, Zhang Yiwen4   

  1. 1. SINOPEC Tianjin Company, Tianjin, 300270;
    2. SINOPEC Engineering Incorporation, Beijing, 100101;
    3. East China University of Science and Technology, Shanghai, 200237;
    4. Shanghai Misu Environmental Protection Technology Co., Ltd., Shanghai, 200237
  • Received:2025-02-17 Revised:2025-08-15 Accepted:2025-08-29 Online:2025-09-15 Published:2025-09-16
  • Contact: Qian Yundong E-mail:shijian.tjsh@sinopec.com

摘要: 渣油是原油蒸馏后的剩余残渣,其由于密度和粘度高、分子结构复杂,加工和利用面临极大挑战。渣油加氢技术因其环保和高轻质油收率的优势,已成为渣油深度加工的关键技术之一。文章主要探讨了高速多级文丘里湿式洗涤器在渣油加氢装置富产低分气净化中的应用,采用流体仿真方法分析了净化器内气流的流动特性,并根据仿真预测的结果优化了洗涤器的设计方案。流体数值计算基于装置原型相同尺寸建模,其计算结果揭示了文丘里内件的流动特性及液滴在高速气流作用下的雾化效果;在此基础上,又进一步耦合后续气液分离模块进行了净化器整体流道仿真,以探究其内部流场特征及液滴在其中的运动行为。依据该研究结果设计的高速文丘里洗涤成套装备在某石化厂渣油加氢装置变压吸附(PSA)原料气净化流程中得到应用,经过现场长周期运行测试,验证了其对H2中杂质气体的高效洗涤性能。该研究可为工业渣油加氢气体净化技术提供理论指导和应用基础,并可在实际生产中得到进一步优化和应用。

关键词: 加氢装置, 高速文丘里, 液滴雾化, 湿式洗涤, NH3吸收, HCl吸收

Abstract: Residual oil, the remnant after crude oil distillation, presents significant challenges for processing and utilization due to its high density, high viscosity, and complex molecular structure. Hydrogenation of residual oil has become one of the key technologies for its deep processing owing to the environmental benefits and high yield of light oils it offers. This study primarily investigates the application of high-speed multi-stage Venturi-type purifier in puri-fying cold low pressure separator gases produced by residual oil hydrogenation. It uses fluid simulation methods to analyze the flow characteristics within the purifier and optimize the purifier design based on the simulation prediction. Fluid numerical calculations are based on models of the same dimensions as the actual device prototypes and the calculation results reveal the flow characteristics within the Venturi components and the atomization effects of liquid droplets under high-speed flow. On this basis, a comprehensive simulation of the purifier flow channels is conducted by further coupling with subsequent gas-liquid separation modules to explore the internal flow field characteristics and the droplet movement behavior within the system. The high-speed Venturi purifying equipment designed on the basis of the research results has been applied in the PSA feed gas purification process of a petrochemical plant's residue oil hydrogenation unit. After long-term operational testing at the industrial site, the efficient wa-shing performance of the high-speed Venturi-type purifier for impurity gases in hydrogen has been validated. This research can provide theoretical guidance and practical basis for gas purification technologies for industrial residual oil hydrogenation, and can be further optimized and applied in actual production.

Key words: hydrogenation unitlhigh-speed Venturildroplet atomizationlwet washinglammonia absorptionlhydrogen chloride absorption