石油化工设备技术 ›› 2024, Vol. 45 ›› Issue (3): 60-66.doi: 10.3969/j.issn.1006-8805.2024.03.013

• 工业炉 • 上一篇    

管式加热炉甲烷掺氢比对燃烧及NOx排放的影响

王文奇,高宇乐,郭晔媛   

  1. 洛阳瑞昌环境工程有限公司,河南 洛阳 471003
  • 收稿日期:2024-03-01 接受日期:2024-04-30 出版日期:2024-05-15 发布日期:2024-07-12
  • 作者简介:王文奇,男,2006年毕业于哈尔滨工业大学热能与动力工程专业,工学学士,现主要从事燃烧及换热设备的研发设计工作,高级工程师。

Effects of Hydrogen Blend Fraction in Methane on Combustion and NOx Emission in Tube Furnace

Wang Wenqi, Gao Yule, GuoYeyuan   

  1. Luoyang Ruichang Environmental Engineering Co., Ltd., Luoyang, Henan, 471003
  • Received:2024-03-01 Accepted:2024-04-30 Online:2024-05-15 Published:2024-07-12

摘要: 文章主要研究管式加热炉甲烷掺氢比对燃烧及NOx排放的影响,为此基于管式加热炉, 分别在1号炉测试圆形燃烧器, 在3号炉测试附墙燃烧器。利用fluent中的FGM燃烧模型耦合GRI-Mech 3.0详细反应机理,结合热态实测烟气温度对其燃烧进行数值计算, 研究分析管式加热炉甲烷掺氢比对燃烧及NOx排放的影响。甲烷掺氢比控制在0%~60%(体积百分数)。研究结果显示: 1)随着掺氢比的提升, 1号炉NOx排放量(标准状态,下同)由75 mg/m3上升至100 mg/m3,3号炉NOx排放量由63 mg/m3下降至50 mg/m3; 2)随着掺氢比的提升,温度高于1 500 ℃时, 1号炉热斑主要分布在燃烧器喷口之内且面积不断增大, 3号炉热斑主要分布在燃烧器喷口之外且面积不断减小; 3)在节能减排方面, 相对于20%的掺氢比, 掺氢比为60%时, 1号炉换热效率提升了4.53%, 3号炉换热效率提升了0.52%,烟气中二氧化碳减排26%;4)上述结果表明,掺氢提升NOx排放,但炉内烟气内循环却减少NOx排放,燃烧器最终的NOx排放结果受到掺氢和烟气内循环综合效果的影响。

关键词: 管式加热炉, 甲烷掺氢比, 热斑, 燃烧试验测量, 试验验证, 数值模拟

Abstract: This paper focuses on studying the effects of hydrogen blend fraction in methane on combustion and NOx emission in tube furnace. Based on a tube furnace, circular burners were tested on furnace #1 and wall-mounted burners were tested on furnace #3. Using Fluent and coupling the FGM combustion model with the detailed reaction mechanism of GRI-Mech 3.0 and the measured temperature of flue gas in hot state, the effects of hydrogen blend fraction in methane on combustion and NOx emission in the tube furnace were numerically calculated. The range of hydrogen blend fraction in methane was controlled between 0% and 60% (hydrogen by volume). The results showed that: 1) as the hydrogen blend fraction increased, NOx emissions increased from 75 mg/Nm3 to 100 mg/Nm3 for furnace #1 and decreased from 63 mg/Nm3 to 50 mg/Nm3 for furnace #3; 2) as the hydrogen blend fraction increased, the hot spot above 1 500 ℃ mainly distributed inside the nozzle of the burner on furnace #1 and kept increasing in area, while it distributed outside the nozzle of the burner on furnace #3 and kept decreasing in area; 3) in terms of energy saving and emission reduction, compared to the hydrogen blend fraction of 20%, the heat transfer efficiency of furnace #1 was improved by 4.53% and that of furnace #3 was improved by 0.52% with a hydrogen blend fraction of 60%, and the carbon dioxide emission reduction in flue gas was 26%; 4) The above results show that hydrogen blend improves NOx emission, but the internal circulation of flue gas in the furnace reduces NOx emission. The final NOx emission result of the burner is affected by the comprehensive effect of hydrogen blend and internal circulation of flue gas.

Key words: tube furnace, hydrogen blend fraction in methane, hot spots, combustion experiment measurement, experimental validation, numerical simulation