石油化工设备技术 ›› 2024, Vol. 45 ›› Issue (1): 15-21.doi: 10.3969/j.issn.1006-8805.2024.01.005

• 腐蚀与防护 • 上一篇    下一篇

气体脱硫装置再生塔腐蚀失效分析及防护

刘祥春   

  1. 中国石化上海石油化工股份有限公司,上海 200540
  • 收稿日期:2023-10-15 接受日期:2023-12-31 出版日期:2024-01-09 发布日期:2024-01-09
  • 作者简介:刘祥春,男,2002年毕业于辽宁石油化工大学化工机械与设备专业,学士,主要从事设备管理工作,高级工程师。

Failure Analysis on Corrosion of Regeneration Tower of Gas Desulfurization Unit and Protection

Liu Xiangchun   

  1. SINOPEC Shanghai Petrochemical Co., Ltd., Shanghai, 200540
  • Received:2023-10-15 Accepted:2023-12-31 Online:2024-01-09 Published:2024-01-09

摘要: 某石化气体脱硫装置再生塔在运行过程中多次出现腐蚀泄漏情况,严重影响装置的正常生产。采用光谱仪、扫描电镜(SEM)、能谱仪(EDS)和X射线衍射仪(XRD)等对腐蚀样品进行了系统的理化分析,同时运用计算流体力学(CFD)模拟软件对塔内流场进行了模拟与分析。结果表明:构件的元素组成符合国标要求,腐蚀产物的主要成分是FeS2。受塔内部结构和生产工艺对流场的影响,在操作工况下系统内局部极易出现湿H2S腐蚀和冲刷腐蚀,这也是导致腐蚀的主要原因。根据再生塔的腐蚀机制,提出了相应的优化措施和对策。

关键词: 再生塔, 腐蚀, 检测, 数值模拟

Abstract: Corrosion and leakage occurred several times during the operation of the regeneration tower of a petrochemical gas desulfurization unit, which seriously affected the normal production of the unit. A systematic physicochemical analysis of the corrosion samples was carried out by means of spectrometer, scanning electron microscope (SEM), energy dispersive spectroscopy (EDS) and X-ray diffraction (XRD), and meanwhile, the flow field in the tower was simulated and analyzed by applying Computational Fluid Dynamics (CFD) simulation software.The results show that the element composition of the component meets the requirements of the national standard. The main component of corrosion products is FeS2. Affected by the internal structure of the tower and production process on the flow field, wet H2S corrosion and erosion corrosion are easy to occur locally in the system, which is the main cause of corrosion. According to the corrosion mechanism, the corresponding optimization measures and countermeasures were put forward.

Key words: regeneration tower, corrosion, detection, numerical simulation